A highly selective and ratiometric fluorescent sensor for relay recognition of zinc(II) and sulfide ions based on modulation of excited-state intramolecular proton transfer

作者：Tang Lijun^*; Cai Mingjun; Zhou Pei; Zhao Jia; Zhong Keli; Hou Shuhua; Bian Yanjiang

来源：RSC Advances, 2013, 3(37): 16802-16809.

DOI：10.1039/c3ra42931h

A new fluorescent 2-(2'-aminophenyl)benzimidazole derivatized sensor BMD was designed and synthesized. In CH3CN/H2O (2 : 8, v/v, HEPES 10 mM, pH 7.4) solution, sensor BMD displays two emission bands and exhibits a highly selective and ratiometric response to Zn2+ ions with a distinctly longer-wavelength emission blue shifted through the inhibition of the excited-state intramolecular proton transfer (ESIPT) process. BMD can clearly discriminate Zn2+ from Cd2+ and other metal ions. Moreover, the in situ generated BMD-Zn2+ solution exhibits a highly selective and ratiometric response to S2- among various anions and thiol-containing amino acids via Zn2+ displacement approach, which results in a revival of the ESIPT phenomenon of free BMD. These results demonstrate that BMD can serve as a ratiometric sensor for sequential recognition of Zn2+ and S2- in aqueous solution through inhibition and turn-on of ESIPT process.

• 出版日期2013
• 单位渤海大学