Hydrothermal Synthesis, Crystal Structure and Properties of a Novel Phosphorus-containing 3D Metal-Organic Cd(II) Coordination Polymer

作者：Mei Chong Zhen^*; Hu Xi Ying; Yang Guang Rui; Li Kai Hui; Shan Wen Wen

来源：Zeitschrift fur Naturforschung Section B-A Journal of Chemical Sciences, 2012, 67(9): 951-955.

DOI：10.5560/ZNB.2012-0153

• 5-(Diphenylphosphino)isophthalic Acid
• P-Cd Interactions
• 3D Metal-Organic Framework

A metal-organic framework [Cd(dppip)](n) (1) based on 5-(diphenylphosphino)isophthalic acid (H(2)dppip) has been synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, and X-ray crystallography. [Cd(dppip)](n) shows a sheet structure owing to carboxylate bridging with windows with dimensions 10.692 x 9.325 angstrom(2). The layers are further connected through P-Cd interactions to give a three-dimensional supramolecular network. The thermal analysis (DTA) of complex 1 exhibited an exceptionally high thermal stability (m. p. 452.8 degrees C). The compound shows fluorescence at ca. 418 nm upon excitation at 314 nm.

• 出版日期2012-9
• 单位华北水利水电大学