Magnetic nanoparticle supported triphenylphosphine ligand for the Rh-catalyzed hydroformylation reaction

作者：Duanmu Chuansong^*; Wu Linlin; Gu Jian; Xu Xingyou; Feng Liangdong; Gu Xu

来源：Catalysis Communications, 2014, 48: 45-49.

DOI：10.1016/j.catcom.2014.01.012

• Hydroformylation
• Magnetic recyclable nano-triphenylphosphine
• Surface cooperation

A magnetic recyclable nano-triphenylphosphine (nano-TPP) ligand was synthesized by simply loading a dopamine-triphenylphosphine derivative onto the surface of super paramagnetic iron oxide nanoparticle (SPION). Via the cooperation between surface neighbor TPP units, nano-TPPs can bond to Rh atoms forming magnetic recyclable nano-TPPRh complexes to catalyze the hydroformylation reaction and can be reused for 20 times with the compensation of Rh salt.

• 出版日期2014-3-10
• 单位淮阴工学院