Extended structures of three new coordination polymers based on 1,10-phenanthroline derivatives and 1,4-benzenedicarboxylate mixed ligands: Preparation, structural characterization and properties

作者：Wang Xiu Li^*; Chen Yong Qiang; Liu Guo Cheng; Zhang Jin Xia; Lin Hong Yan; Chen Bao Kuan

来源：Inorganica Chimica Acta, 2010, 363(4): 773-778.

DOI：10.1016/j.ica.2009.11.038

• Hydrothermal syntheses
• Crystal structure
• 1,10-Phenanthroline derivatives
• Fluorescence Electrochemistry

Three coordination polymers, namely, [Cd(HOIP)(2)(1,4-bdc)] (1), [Cu(HOIP)(1,4-bdc)] (2) and [Cu(PDIP)-(1,4-bdc)] (3) (HOIP = 2-(4-hydroxylbenzene) imidazo[4,5-f] 1,10-phenanthroline, PDIP = 2-(3-pyridine) imidazo[4,5-f] 1,10-phenanthroline, and 1,4-bdc = 1,4-benzenedicarboxylate), have been synthesized under the hydrothermal conditions. All complexes have been characterized by elemental analyses, IR and single-crystal X-ray diffraction. Structural analyses reveal that complex 1 possesses infinite one-dimensional (1D) chain bridged by 1,4-bdc ligands, complexes 2 and 3 both exhibit two-dimensional (2D) (4,4) network structures based on dinuclear [Cu(2)O(2)] units. However, the weak interactions are different in complexes 1-3. Moreover, the thermal properties of all complexes, fluorescence property of 1, and the electrochemical behavior of 3 are also reported in this paper.

• 出版日期2010-3-1
• 单位渤海大学