Differences in the stability of zirconium(IV) complexes related to catalytic phosphine dehydrocoupling reactions

作者:Ghebreab Michael B; Newsham David K; Waterman Rory*
来源:Dalton Transactions, 2011, 40(30): 7683-7685.
DOI:10.1039/c1dt10105f

摘要

Relating to the catalytic dehydrocoupling of secondary phosphine substrates, zirconium phosphide complexes supported by triamidoamine and pentamethylcyclopentadienyl ligands exhibit different stability that is attributed to beta-hydride elimination.

  • 出版日期2011-8