A novel hexairon cluster with one disulfide and two Ph2PCS3- ligands

作者：Shi Yao Cheng^*; Cheng Huan Ren; Cheng Da Cong

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2013, 69(6): 581-+.

DOI：10.1107/S0108270113009049

The title compound, hexadecacarbonylbis{mu(3)-[(diphenylphosphanyl)methanediidyl]sulfanido}-mu(4)-disulfido(2-)-hexairon(4 Fe-Fe), [Fe-6(C13H10PS)(2)(S-2)(CO)(16)], contains two inversion-related [Fe-3(Ph2PCS)(CO)(8)] subclusters linked by an equatorial disulfide bond [S-S = 2.1490 (9) angstrom]. Each Ph2PCS3- ligand is coordinated to a triiron core in mu(3)-kappa P:kappa C-2:kappa S-2 fashion.

• 出版日期2013-6
• 单位扬州大学