Attenuated total reflectance infrared spectroelectrochemistry at a carbon particle electrode; unmediated redox control of a [NiFe]-hydrogenase solution

作者：Healy Adam J; Ash Philip A; Lenz Oliver; Vincent Kylie A^*

来源：Physical Chemistry Chemical Physics, 2013, 15(19): 7055-7059.

DOI：10.1039/c3cp00119a

We report a versatile infrared spectroscopic method for studying redox chemistry of metalloproteins, and demonstrate for the first time electrochemically-induced changes to the active site of the regulatory [NiFe]-hydrogenase from Ralstonia eutropha. A carbon particle network working electrode allows control over a wide potential window without the need for solution mediators.

• 出版日期2013