Ni1-xPtx (x=0-0.12) hollow spheres as catalysts for hydrogen generation from ammonia borane

作者：Cheng, Fangyi; Ma, Hua; Li, Yueming; Chen, Jun^*

来源：Inorganic Chemistry, 2007, 46(3): 788-794.

DOI：10.1021/ic061712e

• NUCLEAR MAGNETIC RESONANCE
• METAL-ORGANIC FRAMEWORK
• N-H COMPOUNDS
• THERMAL-DECOMPOSITION
• AMINE-BORANE
• STORAGE MATERIALS
• DEHYDROGENATION
• HYDROLYSIS
• NANOTUBES
• RELEASE

In this paper, nest-like Ni1-xPtx (x = 0, 0.03, 0.06, 0.09, and 0.12) hollow spheres of submicrometer sizes have been prepared through a template-replacement route and investigated as catalysts for generating hydrogen from ammonia borane (NH3BH3). Experimental investigations have demonstrated that the obtained Ni1-xPtx alloy hollow spheres exhibit favorable catalytic activities for both the hydrolysis and the thermolysis of NH3BH3. It was found that, in the presence of the Ni0.88Pt0.12 catalyst, the hydrolysis of NH3BH3 causes a quick release of H-2, while the thermal decomposition of NH3BH3 occurs at lowered temperatures with increased mass loss. The present results indicate that NH3BH3 along with Ni1-xPtx alloy hollow spheres may find some applications for small-scale on-board hydrogen storage and supply.

• 出版日期2007-2-5
• 单位南开大学