A novel strategy for clean and selective oxygenation of hydrocarbons with n-Bu4NHSO5 in neat water catalyzed by recyclable water-insoluble iron (III) tetraphenylporphyrins

作者：Rezaeifard Abdolreza^*; Jafarpour Maasoumeh; Naeimi Atena; Kaafi Samira

来源：Catalysis Communications, 2011, 12(8): 761-765.

DOI：10.1016/j.catcom.2011.01.013

• Porphyrin
• Peroxomonosulfate
• Oxygenation
• Hydrocarbons
• Water

A novel heterogeneous method for efficient oxygenation of olefins to epoxides and saturated hydrocarbons to the related ketones using tetrabutylammonium peroxomonosulfate (n-Bu4NHSO5) in neat water catalyzed by Fe(TPP)Cl and Fe(TDCPP)Cl complexes as water-insoluble catalysts has been developed. The oxidation system proceeds well in the absence of organic co-solvents and surfactants. The electron-deficient Fe(TDCPP)Cl catalyst could easily be recycled and reused without loss of activity and the oxidant's by-product (n-Bu4NHSO4) could also be recycled.

• 出版日期2011-3-31