Bonding titanium on multi-walled carbon nanotubes for hydrogen storage: An electrochemical approach

作者：Brieno Enriquez K M; Ledesma Garcia J; Perez Bueno J J^*; Godinez Luis A; Terrones H; Angeles Chavez C

来源：Materials Chemistry and Physics, 2009, 115(2-3): 521-525.

DOI：10.1016/j.matchemphys.2009.02.004

• Hydrogen storage
• Multi-walled carbon nanotubes
• Titanium bonding
• Electrochemical

This work explores the use of some procedures, involving electrochemistry, in order to bond atomic Ti on the outer surface of multi-walled carbon nanotubes (MWNTs). It is assumed that each titanium atom has the potential of host up to four hydrogen molecules and relinquish them by heated. As a way to spread and stick nanotubes on an electrode, a tested route was drying a solution with nanotubes on a glassy carbon flat electrode. The MWNTs were treated by anodic polarization in organic media. Dichloromethane was selected as the medium and titanium tetrachloride as the precursor for attaching atomic Ti onto the nanotubes. The hydrogen adsorption, estimated from voltamperometry was five times higher on Ti-MWNTs that on bare nanotubes. The use of anodic polarization during the preparation of Ti-MWNTs may represent great significance in procedure, which was manifest during the voltamperometric evaluation of samples.

• 出版日期2009-6-15