Alkaline Earth Metal Salts of 5,5 '-Bistetrazole - from Academical Interest to Practical Application

作者：Fischer Niko; Klapoetke Thomas M; Peters Kristina; Rusan Magdalena; Stierstorfer Joerg

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2011, 637(12): 1693-1701.

DOI：10.1002/zaac.201100263

• Alkaline earth metals
• Tetrazoles
• Crystal structures
• IR spectroscopy
• Pyrotechnics

The alkaline earth metal salts of 5,5 '-BT, [Be(H(2)O)(4)](5,5 '-BT)center dot H(2)O (1), [Mg(H(2)O)(6)(5,5 '-BT)center dot 3H(2)O (2), [Ca(H(2)O)(4)(5,5 '-BT)]center dot H(2)O (3), [Sr(H(2)O)(4)(5,5 '-BT)]center dot 2DMF (4), and [Ba(H(2)O)(4)(5,5 '-BT)] (5) were fully characterized by low temperature X-ray diffraction, vibrational (IR, Raman) and NMR spectroscopy, elemental analysis and differential scanning calorimetry (DSC). A detailed description of the crystal structures is given. In addition, the potential use of 4 and 5 in coloring pyrotechnical compositions was investigated.

• 出版日期2011-10