Advances in Liquid Crystalline Conjugated Polymers

作者：Akagi Kazuo^*

来源：Journal of Polymer Science Part A: Polymer Chemistry , 2009, 47(10): 2463-2485.

DOI：10.1002/pola.23277

• alignment
• conjugated polymers
• chiral smectic C phase
• ferroelectricity
• linearly polarized emission
• liquid crystallinity
• macroscopic alignment
• memory function
• photoswitching
• polyphenylene derivatives

We review advances in liquid crystalline (LC) conjugated polymers by focusing on (i) ferroelectric and (ii) photoresponsive LC conjugated polymers. In Part 1, LC polyphenylene derivatives were synthesized through substitution of fluorine-containing chiral LC groups into side chains. Poly (para-phenylene) [P1] and poly (meta-phenylene) [P2] derivatives showed chiral smectic C phases responsible for ferroelectricity. They exhibited quick response to electric field, giving switching times of <1 s between two bistable states. The spontaneous polarization (P(S)) of P2 remained Unchanged even after the electric field became zero, affording the residual polarization (PR) whose value was the same as that of P(S). This indicates that P2 has a potential memory function based on FLC nature. In Part 2, poly (para-phenylenevinylene) [P5] and poly(bithienylene-phenylene) [P6] derivatives were synthesized by introducing dithienylethene moieties into side chains. Drastic quenching of fluorescence occurred when the photoresponsive moiety changed from an open form to a closed one upon an irradiation of ultraviolet light. The quenched fluorescence was recovered through a photo-isomerization from the closed form to the open one. Macroscopically aligned P6 film exhibited a linearly polarized fluorescence with significant anisotropy. Reversible quenching and emitting behavior in anisotropic fluorescence was controlled by the photochemical Switching.

• 出版日期2009-5-15