An iron-catalysed hydrosilylation of ketones

作者:Nishiyama Hisao*; Furuta Akihiro
来源:Chemical communications, 2007, (7): 760-762.
DOI:10.1039/b617388h

摘要

The combination of Fe(OAc)(2) and multi-nitrogen-based ligands such as N,N, N', N'-tetramethyethylenediamine, bis-tert-butyl-bipyridine, or bis(oxazolinyl) pyridine can efficiently catalyse hydrosilylation of ketones to give the corresponding alcohols in high yields including asymmetric catalysis.

  • 出版日期2007