A New 6-Connected Ni(II) Complex With 5-methylisophthalic Acid: Synthesis, Crystal Structure, and Properties

作者：Chang Xin Hong^*; Sun Xiao Yuan

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2013, 43(3): 279-282.

DOI：10.1080/15533174.2012.740721

• 1
• 6-bis(1
• 2
• 4-triazol-1-yl)hexane
• 5-methylisophthalic acid
• crystal structure
• Ni(II) complex

A new Ni(II) metalorganic coordination polymer, {[Ni(mip) (1,6-bth)(H2O)]center dot H2O}n (1), (H2mip = 5-methylisophthalic acid, 1,6-bth = 1,6-bis(1,2,4-triazol-1-yl)hexane), was assembled under hydrothermal condition by the reactions of Ni(II) acetate with H2mip and 1,6-bth. Compound 1 was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. The results reveal that compound 1 consists of mip anion-bridged 1D NiII chains that are linked by 1,6-bth into a 2D layer. In addition, the thermal stability of 1 was briefly investigated.

• 出版日期2013-3-1
• 单位洛阳师范学院; 贵州工程应用技术学院