科研之友
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摘要
Two unique silver nanoclusters protected by alkynyl and diphosphine ligands have been synthesized. Single crystal structural determination reveals that they have a centered anticuboctahedral Ag-13 kernel. Such a kernel is observed for the first time in a coinage metal nanocluster. This work offers new insights into the fact that the PhC equivalent to C ligand represents a new direction in synthesizing novel metal nanoclusters.
