Preparation and catalytic activity of bioactive fibers

作者：Yu yuan Yao; Wen xing Chen^*; Bao yan Zhao; Shen shui Lu

来源：Chinese Journal of Polymer Science, 2006, 24(5): 441-447.

DOI：10.1142/S0256767906001503

• silk fibers
• viscose fibers
• bioactive fibers
• mimic enzyme
• metallophthalocyanine
• catalytic oxidation

Two kinds of water-soluble metallophthalocyanines, binuclear cobalt phthalocyanine (Co2Pc2) and binuclear ferric phthalocyanine (Fe2Pc2), were synthesized through phenylanhydride-urea route and characterized by elemental analysis and FT-IR spectra. Binuclear metallophthalocyanine derivatives (Mt(2)Pc(2)) were immobilized on silk fibers and modified viscose fibers to construct bioactive fibers of mimic enzyme. Mt(2)Pc(2) was used as the active center of bioactive fibers, viscose and silk fibers as the microenvironments. The catalytic oxidation ability of bioactive fibers on the malodors of methanthiol and hydrogen sulfide was investigated at room temperature. The experimental results indicated that the catalytic activity of such bioactive fibers was closely correlative to the types of bioactive fibers and substrates.

• 出版日期2006-9
• 单位浙江理工大学