High-performance membranes from polyimides with intrinsic microporosity

作者:Ghanem Bader S; McKeown Neil B*; Budd Peter M; Selbie James D; Fritsch Detlev
来源:Advanced Materials, 2008, 20(14): 2766-+.
DOI:10.1002/adma.200702400

摘要

Membranes with high permeability to gases are formed from polyimides with rigid backbones that incorporate a spiro-centre (see figure). A route to this new range of high-free-volume polyimides is demonstrated, and exceptional performance is obtained for a polymer containing a dimethyl binaphthyl unit.

  • 出版日期2008-7-17