A low-temperature extraction-solvothermal route to the fabrication of micro-sized MoS2 spheres modified by Cyanex 301

作者：Shi HQ; Fu X^*; Zhou X; Wang DB; Hu ZS

来源：Journal of Solid State Chemistry, 2006, 179(6): 1690-1697.

DOI：10.1016/j.jssc.2006.02.030

• molybdenum disulfide
• micro-spheres
• extraction-solvothermal
• Cyanex 301
• oil additive

Mono-dispersed molybdenum disulfide micro-spheres with the diameter of 1-3 mu m have been successfully synthesized via extraction-solvothermal method at 150 degrees C. The extractant Cyanex 301 (di-(2,4,4-trimethylpentyl) dithiophosphinic acid) acted as phase transferring agent, reductant, sulfur source and morphology-controlling agent in the whole procedure. The obtained MoS, micro-spheres were characterized by XRD, EDS, SEM, TEM, HRTEM, IR, UV-Vis and TG, respectively. The influences of reaction conditions were discussed while a mechanism was proposed to explain the formation of the micro-spheres. Moreover, the tribological properties of liquid paraffin (LP) containing Cyanex 301-modified MoS2 micro-spheres were also evaluated on a four-ball machine, showing that the obtained MoS, product was an excellent oil additive in LP and such lubricant had good anti-wear and friction- reducing properties.

• 出版日期2006-6
• 单位青岛科技大学