A spin-canted Ni-4(II)-based metal-organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons

作者：Li, Jia; Guo, Ying; Fu, Hong-Ru; Zhang, Jian; Huang, Rong-Bin; Zheng, Lan-Sun; Tao, Jun^*

来源：Chemical Communications, 2014, 50(65): 9161-9164.

DOI：10.1039/c4cc02396j

• CARBON-DIOXIDE CAPTURE
• MAGNETIC-PROPERTIES
• CO2
• SEPARATION
• CROSSOVER
• CRYSTAL
• SITES

The reaction of nickel(II) nitrate with isonicotinic acid and 2,6-dimethyl-pyridine-3,5-dicarboxylic acid affords a novel, tetranuclear nickel(II)based metal-organic framework that exhibits spin-canted antiferromagnetism with a canted angle of 1.65 degrees and high adsorptive selectivity for light hydrocarbons.

• 出版日期2014-8-21
• 单位中国科学院福建物质结构研究所; 厦门大学