A one-step, cost-effective green method to in situ fabricate Ni(OH)(2) hexagonal platelets on Ni foam as binder-free supercapacitor electrode materials

作者：Li, Lingjie; Xu, Jing; Lei, Jinglei^*; Zhang, Jie; McLarnon, Frank; Wei, Zidong; Li, Nianbing; Pan, Fusheng

来源：Journal of Materials Chemistry A, 2015, 3(5): 1953-1960.

DOI：10.1039/c4ta05156d

• DOUBLE-LAYER CAPACITORS
• ALL-SOLID-STATE
• HIGH-PERFORMANCE
• NICKEL FOAM
• ENERGY-STORAGE
• GRAPHENE
• HYDROXIDE
• NANOSTRUCTURES
• NANOSHEETS
• AEROGELS

Nickel hydroxide (Ni(OH)(2)) is considered to be a promising alternative to the expensive and toxic RuO2 electrode material for high-performance supercapacitors; however, the fabrication method and electrochemical performance of suitable Ni(OH)(2) structures are unsatisfactory. In the present work, a facile, cost-effective green method is developed to in situ fabricate Ni(OH)(2) hexagonal platelets on Ni foam as a binder-free supercapacitor electrode with high performance. The Ni(OH)(2) hexagonal platelets are self-grown on three-dimensional (3D) Ni foam by a one-step hydrothermal treatment of Ni foam in a 15 wt% H2O2 aqueous solution without the use of nickel salts, acids, bases, or post-treatments. The asprepared Ni(OH)(2) hexagonal platelets-Ni foam (HNF) electrode can be used directly as a supercapacitor electrode material, thereby avoiding the need for binders and conducting agents. The Ni(OH)(2) hexagonal platelets demonstrate high capacitance (2534 F g(-1) at a scan rate of 1 mV s(-1)) and excellent cycling stability (97% capacitance retention after 2000 cycles at a scan rate of 50 mV s(-1)). The fabrication method developed here has the significant advantage of low-cost, facile, green, and additive-free processing, and it is therefore a promising route for preparing self-supported metal (hydr) oxide electrodes for high-performance supercapacitors and other energy-storage devices.

• 出版日期2015
• 单位重庆大学