科研之友
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摘要
The reaction of uranyl ions with azelaic or dodecanedioic acids under solvohydrotherrnal conditions leads to crystallization of anionic dinudear cage compounds with [M(bipy/phen)(3)](2+) counterions (M = 3d-block cation), while the smaller suberic acid yields heterometallic metallacycles. Complexes with the longer aliphatic chains are the first triple-stranded helicates reported in actinide chemistry.
- 出版日期2015-11-16
- 单位中国地震局
