A novel 1,8-naphthalimide derivative with an open space for an anion: unique fluorescence behaviour depending on the binding anion's electrophilic properties

作者：Izawa Hironori^*; Nishino Shoji; Sumita Masato; Akamatsu Masaaki; Morihashi Kenji; Ifuku Shinsuke; Morimoto Minoru; Saimoto Hiroyuki

来源：Chemical Communications, 2015, 51(41): 8596-8599.

DOI：10.1039/c5cc01709b

We have designed a novel 1,8-naphthalimide derivative with an open space for an anion. Computational calculation has predicted that the space could trap various anion species and photo-induced charge transfer depending on the anion's electrophilic properties. Indeed, the fluorescence behaviour of the 1,8-naphthalimide derivative complexes with each anion is consistent with the computational prediction.

• 出版日期2015