摘要
Palladium complexes bearing abnormal N-heterocyclic carbene were used as catalysts in Suzuki-Miyaura cross coupling of aryl chlorides at 25 degrees C. The catalyst remained active for 10 successive catalytic runs and can activate 4-chlorotoluene at 25 degrees C with 0.01 mol% catalyst loading resulting in a TON of 9500 within 6 h.
- 出版日期2012-1-14