科研之友
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摘要
Self-assembly of block polymers under confined states is found to be affected by various parameters, such as the geometry and surface effect of confined states, which make the phase behavior of polymers under confined states different from those in bulk state. A stack of novel nanostructures have been fabricated by the self-assembly of block polymers under confined states. Furthermore, to study the self-assembly process of block polymers under confined states could give a deep understanding on the phase behavior of block polymers. The similar or covered phase behaviors in bulk state could be clearly distinguished under confined states. In this review, the cylinder-forming linear block polymers are detailed studied using computer simulation methods. The geometry and surface fields of confined states and the component of polymer chains are considered separately.
