Dismantling the salen framework: design of new asymmetric silylcyanation catalysts

作者:Ternel Jeremy*; Roussel Pascal; Agbossou Niedercorn Francine; Gauvin Regis M
来源:Catalysis Science & Technology, 2013, 3(3): 580-583.
DOI:10.1039/c2cy20818k

摘要

A series of novel chiral phenoxyimine Al(III) complexes catalyzes asymmetric addition of SiMe3CN to a broad range of aldehydes with high yields and good to excellent enantioselectivities in the presence of a Lewis base.

  • 出版日期2013