Aqua(picolinato N-oxide-k(2)O(1),O-2)-pyridine-2,6-dicarboxylato-k(3)O,N,O ')iron(III) monohydrate

作者：Han Dongdong; Wang Dong'e

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M1343-U3153.

DOI：10.1107/S1600536808030663

In the title compound, [Fe(C6H4NO3)(C7H3NO4)(H2O)] center dot H2O, the Fe III ion is coordinated by two O and one N atoms from a pyridine-2,6-dicarboxylate ligand, by two O atoms from a picolinate N-oxide ligand and by one water O atom in a distorted octahedral geometry [Fe - O = 1.940 ( 3) - 2.033 ( 3) angstrom and Fe - N = 2.057 (4) angstrom]. In the crystal structure, the coordinated and solvent water molecules contribute to the formation of O - H center dot center dot center dot O hydrogen bonds, which link the molecules into layers parallel to the ab plane.

• 出版日期2008-10
• 单位喀什大学; 浙江医药高等专科学校