New Fluorinated Dithienyldiketopyrrolopyrrole Monomers and Polymers for Organic Electronics

作者：Bura Thomas; Beaupre Serge; Ibraikulov Olzhas A; Legare Marc Andre; Quinn Jesse; Leveque Patrick; Heiser Thomas; Li Yuning; Leclerc Nicolas; Lederc Mario

来源：Macromolecules, 2017, 50(18): 7080-7090.

DOI：10.1021/acs.macromol.7b01198

Diketopyrrolopyrrole (DPP) derivatives are among the most efficient materials studied for both polymer solar cells (PSCs) and organic field-effect transistors (OFETs) applications. We report here the synthesis of new fluorinated dithienyldiketopyrrolopyrrole (fDT-DPP) monomers suitable for direct heteroarylation polymerization. fDT-DPP copolymers were then prepared to probe the effect of the fluorination. It was found that they feature deeper HOMO energy levels and smaller bandgaps than their non-fluorinated analogues. Moreover, some fDT-DPP copolymers show ambipolar behavior when tested in OFETs. For example, P2 shows hole mobility up to 0.8 cm(2) V-1 s(-1) and electron mobility up to 0.5 cm(2) V-1 s(-1). Inverted PSCs with power conversion efficiency (PCE) up to 7.5% were also obtained for PS. These results reported here (OFETs and PSCs) confirm that the fluorination of dithienyl-DPP moieties improves the performance of organic electronics devices. This study is also evidencing the strength of the direct heteroarylation polymerization and fDT-DPP as a new class of conjugated polymers.

• 出版日期2017-9-26