Secondary building units, nets and bonding in the chemistry of metal-organic frameworks

作者：Tranchemontagne David J; Mendoza Cortes Jose L; O'Keeffe Michael; Yaghi Omar M^*

来源：Chemical Society Reviews, 2009, 38(5): 1257-1283.

DOI：10.1039/b817735j

This critical review presents a comprehensive study of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) towards construction and synthesis of metal-organic frameworks (MOFs). We describe the geometries of 131 SBUs, their connectivity and composition. This contribution presents a comprehensive list of the wide variety of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) in the construction and synthesis of metal-organic frameworks. The SBUs discussed here were obtained from a search of molecules and extended structures archived in the Cambridge Structure Database (CSD, version 5.28, January 2007) which included only crystals containing metal carboxylate linkages (241 references).

• 出版日期2009