Aldol reactions mediated by a tetrahedral boronate

作者:Muller Tobias; Djanashvili Kristina; Arends Isabel W C E; Peters Joop A; Hanefeld Ulf*
来源:Chemical Communications, 2013, 49(4): 361-363.
DOI:10.1039/c2cc37047f

摘要

The base is a key factor in aldol reactions in organicmedia, determining the selectivity. Here, we describe a tetrahedral phenylboronate salt as a mild non-nucleophilic base that is able to catalyse the aldol reaction and significantly decrease the formation of undesired elimination products.

  • 出版日期2013

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