A facile strategy for the synthesis of hierarchical CuO nanourchins and their application as non-enzymatic glucose sensors

作者：Sun, Shaodong; Zhang, Xiaozhe; Sun, Yuexia; Zhang, Jie; Yang, Shengchun; Song, Xiaoping; Yang, Zhimao^*

来源：RSC Advances, 2013, 3(33): 13712-13719.

DOI：10.1039/c3ra41098f

• CARBOHYDRATE OXIDATION
• COPPER ELECTRODES
• SIMPLE ROUTE
• CU2O
• NANOSPHERES
• OXIDE
• SUPERCONDUCTIVITY
• NANOSTRUCTURES
• NANOPARTICLES
• NANORIBBONS

We have demonstrated a facile strategy for synthesizing hierarchical CuO nanourchins (<300 nm) made from nanopetal building blocks by using a Cu2O-templated oxidative method. These hierarchical CuO nanourchins can serve as a promising electrode material and display an excellent response to glucose in comparison to interfering agents that normally co-exist in solution (such as ascorbic acid, uric acid and sodium chloride). The linear detection range is estimated to be from 50 mu M to 5 mM at + 0.57 V vs. Ag/AgCl (correlation coefficient = 0.9996), and the sensitivity is 1634 mu A mM(-1) cm(-2). The as-prepared hierarchical CuO nanourchins open up a new avenue for exploring the synthesis of highly sensitive CuO nanostructures for potential applications in the field of enzyme-free amperometric sensing of glucose. Significantly, it is anticipated that different nanostructured Cu2O templates can be utilized to synthesize new forms of CuO nanomaterial.

• 出版日期2013
• 单位西安交通大学