A novel coordination polymer with double chains structure: hydrothermal syntheses, structures and magnetic properties of [Cu(phen)(H2O)(2)SO4](n) (phen=1, 10-phenanthroline)

作者：Xu L; Wang EB^*; Peng J; Huang RD

来源：Inorganic Chemistry Communications, 2003, 6(6): 740-743.

DOI：10.1016/S1387-7003(03)00055-8

• hydrothermal syntheses
• copper(II)
• coordination polymer
• one-dimensional chain
• magnetic properties

A coordination polymer [Cu(phen)(H2O)(2)(SO4)](n), (1) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single crystal X-ray diffraction. This compound displays a novel double chains structure, in which each one-dimerisional chain is constituted by the distorted octahedral complex of copper(II) bridged through bidentate sulfate, ligands. Magnetic susceptibility measurement of 1 has been performed down to 2 K. Although paramagnetic behavior is dominantly manifested, compound 1 shows a weak antiferromagnetic interaction on cooling from room temperature to 2 K.

• 出版日期2003-6
• 单位东北师范大学