An Open Neodymium-Organic Framework with the NbO Structure Type Based on Binuclear SBU Involved In Situ Generated Formate

作者：Dai Fangna; Cui Peipei; Ye Fei; Sun Daofeng^*

来源：Crystal Growth & Design, 2010, 10(4): 1474-1477.

DOI：10.1021/cg1000914

The solvothermal reaction of Nd(NO(3))(3)center dot 6H(2)O and 5-amino-2,4,6-triiodoisophthalic acid (H(2)atiip) in DMF/ethonal/H(2)O (5:2:1) in the presence of pyridine gave rise to a new open neodymium-organic framework having the NbO structure type, [Nd(HCOO)(atiip)(DMF)(2)]center dot DMF center dot H(2)O (1). Complex I can keep its diffraction pattern even after being heated to 200 degrees C.

• 出版日期2010-4
• 单位山东大学