A novel 3D coordination polymer [Cd-15([mu(4)-Mtta)(12)(mu(3)-Mtta)(6)(mu(3)-SO4)(4)(mu(3)-OH)(4)]: Synthesis, structure and solid properties

作者：Ding You Bang; Cheng Ying; Zhang Zhi Ling; Zhang Jing; Yin Ye Gao^*; Gao Wen Hua

来源：Inorganic Chemistry Communications, 2009, 12(1): 45-47.

DOI：10.1016/j.inoche.2008.11.001

• Cadmium (II)
• Tetrazole
• Coordination polymer
• In situ synthesis
• Fluorescence

A 3D coordination polymer, {[Cd-15(mu(4)-Mtta)(12)(mu(3)-Mtta)(6)(mu(3)-SO4)(4)(mu(3)-OH)(4)] center dot 6H(2)O]}(n) (1) (Mtta = 5-methyl-tetrazolate), which shows the rare multifunction of in situ formed Mtta and bright photo-induced blue emission, was isolated from a hydrothermal reaction of CdSO4 center dot 8/3H(2)O, NaN3 in acetonitrile and water.

• 出版日期2009-1
• 单位汕头大学