A Mild and Efficient Procedure for the N-Functionalization of S-Perfluoroalkylated Aryl Sulfoximines

作者:Mace Yohan; Constant Urban Celine; Bouvet Sebastien; Pegot Bruce; Bournaud Chloee; Toffano Martial; Giang Vo Thanh*; Diter Patrick; Magnier Emmanuel
来源:Synthesis, 2013, 45(11): 1505-1512.
DOI:10.1055/s-0033-1338440

摘要

N-Acylated perfluoroalkylated sulfoximines are synthesized easily from the corresponding free NH-sulfoximines on reaction with acid chlorides. This mild procedure is extended to diacid chlorides for the preparation of dimeric N-bridged sulfoximines and to reactions with chloroformates, carbamoyl chlorides, chlorothionoformates and thiocarbamoyl chlorides as electrophiles.

  • 出版日期2013-6