Nanocatalysts based on dendrimers

作者：Karakhanov Edward A^*; Maximov Anton L; Skorkin Vitaliy A; Zolotukhina Anna V; Smerdov Alexey S; Tereshchenko Andrey Yu

来源：Pure and Applied Chemistry, 2009, 81(11): 2013-2023.

DOI：10.1351/PAC-CON-08-10-15

• catalysis
• dendrimer complexes
• hydrogenation
• palladium nanoparticles
• Wacker oxidation

Nanostructured regular materials based on dendrimers bound by covalent or coordination bonds between surface functional groups were synthesized. Bimetallic Cu(II) and Pd(II) metal complexes with nitrile-based dendrimers demonstrated high activity in Wacker oxidation of terminal alkenes along with good selectivity for methylketone formation. New heterogeneous catalysts based on Pd nanoparticles and cross-linked polypropylene imine (PPI) and polyamidoamine (PAMAM) dendrimers were prepared and examined for selective hydrogenation of unsaturated compounds.

• 出版日期2009-11