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摘要
Nanoporous crystals of discrete stacks of metallo-porphyrins together with exogenous metal centers have been obtained by synergistic non-covalent interactions of tetra-cationic copper(II)-meso-tetrakis(4-N-methylpyridyl)porphyrin and polyanionic tetrasulfonato-tetrakis(hydroxylcarbonylmethoxy)calix[4]arene building blocks successively functionalized by diffusion and coordination of Zn(2+) or Ni(2+) ions.
- 出版日期2010
