Molecular structure and electrochemistry of carbon-bridged diferrocenyl compounds

作者：Xie, Rui-Jun; Han, Li-Min^*; Suo, Quan-Ling; Hong, Hai-Long; Luo, Mei-Hua

来源：Journal of Coordination Chemistry, 2010, 63(10): 1700-1710.

DOI：10.1080/00958972.2010.487102

• Diferrocene
• Electrochemical interaction
• Carbon-bridge
• Substituent

Four diferrocenyl compounds: FcC(CH3)2Fc (1), Fc(CH3)C(C2H5)Fc (2), Fc(CH3)C(C3H7)Fc (3), and Fc(CH3)C(C6H5)Fc (4) were synthesized and characterized by NMR, FT-IR, MS, and elemental analysis. The molecular structures were determined by using X-ray single crystal diffraction. The electrochemical interactions between two ferrocenyl units in these compounds were investigated by cyclic voltammetry and theoretical calculation. The electron density of bridging carbon was a key factor for the separation of two ferrocenyl units.

• 出版日期2010
• 单位内蒙古工业大学