Dehydrogenative Diels-Alder Reaction

作者:Ozawa Takuya; Kurahashi Takuya; Matsubara Seijiro*
来源:Organic Letters, 2011, 13(19): 5390-5393.
DOI:10.1021/ol202283d

摘要

The dehydrogenative cycloaddition of dieneynes, which possess a diene in the form of a styrene moiety and a dienophile in the form of an alkyne moiety, produces naphthalene derivatives when heated. It was found that a key requirement of this process is the presence of a silyl group attached to the alkyne moiety, which forces a dehydrogenation reaction to occur.

  • 出版日期2011-10-7