Assembly of a multilayer film and catalytic application in Suzuki cross-coupling reaction based on synergistic effects of a conjugated organometallic pyridyl Pt(C C)(2) moiety with palladium

作者：Li, Xing^*; Zhao, Xiuhua; Zhang, Jie; Zhao, Yayun

来源：Chemical Communications, 2013, 49(85): 10004-10006.

DOI：10.1039/c3cc44439b

A multilayer film(Pd2+/1)(n) was prepared with Pd(II) ions and platinum compound trans-[Pt(PPh3)(2)(C CPy)(2)] (1) using the layer-by-layer self-assembly method. The film loaded on the quartz slide could be capable of discharging high catalytic active Pd species to promote the C-C coupling reaction, with extraordinarily low Pd-loading (6.6 x 10(-6) mol%) and high catalytic efficiency in H2O-EtOH solution.

• 出版日期2013
• 单位宁波大学; 湘潭大学