Addition of alkynes to digermynes: experimental insight into the reaction pathway

作者：Tashkandi Nada Y; Pavelka Laura C; Caputo Christine A; Boyle Paul D; Power Philip P; Baines Kim M^*

来源：Dalton Transactions, 2016, 45(17): 7226-7230.

DOI：10.1039/c6dt01015f

The addition of an alkynyl cyclopropyl mechanistic probe to a digermyne did not lead to any ring-opened rearrangement products indicating that the reaction pathway does not involve any vinylic radicals or cations and providing experimental insight into the addition of alkynes to digermynes.

• 出版日期2016