A truncated [Mn-12(III)] tetrahedron from oxime-based [(Mn3O)-O-III] building blocks

作者：Frost J M; Sanz S; Rajeshkumar T; Pitak M B; Coles S J; Rajaraman G^*; Wernsdorfer W; Schnack J; Lu**y P J; Brechin E K

来源：Dalton Transactions, 2014, 43(28): 10690-10694.

DOI：10.1039/c4dt01469c

The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn-12(III)] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.

• 出版日期2014