A kinetic study of mechanochemical halogen bond formation by in situ P-31 solid-state NMR spectroscopy

作者:Xu Yijue; Champion Lysiane; Gabidullin Bulat; Bryce David L
来源:Chemical Communications, 2017, 53(71): 9930-9933.
DOI:10.1039/c7cc05051h

摘要

In situ P-31 solid-state NMR studies of halogen bond formation between triphenylphosphine oxide and para-diiodotetrafluorobenzene provide insights into the cocrystallisation process and provide an estimate of the activation energy. The effects of temperature, magic-angle spinning speed, and initially added liquid on the reaction rate and mechanism have been investigated.

  • 出版日期2017-9-14