Manipulation and control of the interfacial polarization in organic light-emitting diodes by dipolar doping

作者：Jaeger Lars; Schmidt Tobias D; Bruetting Wolfgang

来源：AIP Advances, 2016, 6(9): 095220.

DOI：10.1063/1.4963796

Most of the commonly used electron transporting materials in organic light-emitting diodes exhibit interfacial polarization resulting from partially aligned permanent dipole moments of the molecules. This property modifies the internal electric field distribution of the device and therefore enables an earlier flat band condition for the hole transporting side, leading to improved charge carrier injection. Recently, this phenomenon was studied with regard to different materials and degradation effects, however, so far the influence of dilution has not been investigated. In this paper we focus on dipolar doping of the hole transporting material 4,4-bis[N-(1-naphthyl)-N-phenylamino]-biphenyl (NPB) with the polar electron transporting material tris-(8-hydroxyquinolate) aluminum (Alq(3)). Impedance spectroscopy reveals that changes of the hole injection voltage do not scale in a simple linear fashion with the effective thickness of the doped layer. In fact, the measured interfacial polarization reaches a maximum value for a 1:1 blend. Taking the permanent dipole moment of Alq(3) into account, an increasing degree of dipole alignment is found for decreasing Alq(3) concentration. This observation can be explained by the competition between dipole-dipole interactions leading to dimerization and the driving force for vertical orientation of Alq(3) dipoles at the surface of the NPB layer.

• 出版日期2016-9