A new 3D metal-organic framework based on a hexanuclear cobalt(II): Synthesis, structure, and magnetic property

作者：Liu Shuang; Gao Hong Ling^*; Cui Jian Zhong

来源：Inorganic Chemistry Communications, 2015, 55: 14-16.

DOI：10.1016/j.inoche.2015.02.022

• 1H-1,2,4-triazole
• Metal-organic framework
• Hexanuclear cluster
• Magnetic property

A new 3D framework 1 based on {Co-6} cluster as node was successfully synthesized and fully characterized, which showed an 8-connected bcu topology with the Schlafli symbol of {4(24),6(4)). Furthermore, the thermal stability and magnetic property reveal that 1 displays high thermal stability and antiferromagnetic interaction among the Co-II spin carries.

• 出版日期2015-5
• 单位天津大学