A Stable Amino-Functionalized Interpenetrated Metal-Organic Framework Exhibiting Gas Selectivity and Pore-Size-Dependent Catalytic Performance

作者：Fan, Weidong; Wang, Yutong; Xiao, Zhenyu; Zhang, Liangliang; Gong, Yaqiong^*; Dai, Fangna; Wang, Rongming; Sun, Daofeng^*

来源：Inorganic Chemistry, 2017, 56(22): 13634-13637.

DOI：10.1021/acs.inorgchem.7b02148

• COORDINATION POLYMER
• HYDROGEN UPTAKE
• AMIDE GROUPS
• ADSORPTION
• CO2
• SORPTION
• STORAGE
• ISOMERS

An amino-functionalized doubly interpenetrated microporous zinc metal-organic framework (UPC-30) has been solvothermally synthesized. UPC-30 can be stable at 190 degrees C and confirmed by powder X-ray diffraction. Gas adsorption measurements indicate that UPC-30 exhibits high H-2 adsorption heat and CO2/CH4 separation efficiency. After the exchange of Me2NH2+ by Li+ in the channels, the H-2 adsorption heat increased by 19.7%. Because of the existence of -NH2 groups in the channels, UPC-30 can effectively catalyze Knoevenagel condensation reactions with high yield and pore-size-dependent selectivity.

• 出版日期2017-11-20
• 单位中国石油大学（华东）; 中北大学