Dehydrogenation of inert alkyl groups via remote C-H activation: Converting a propyl group into a pi-allylic complex

作者：Giri Ramesh; Maugel Nathan; Foxman Bruce M; Yu Jin Quan^*

来源：Organometallics, 2008, 27(8): 1667-1670.

DOI：10.1021/om8000444

Pd(OAC)(2)-inediated dehydrogenation of an alkyl group to a double bond or a eta(3)-allylic complex via sp(3) C-H bond activation and allylic oxidation is reported. A novel redox is Proposed for this double oxidation under oxidant-free conditions. A catalytic protocol using benzoquinone as the stoichiometric oxidant has also been developed for the dehydrogenation of cyclopentylcarboxamides.

• 出版日期2008-4-28