科研之友
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摘要
A one-pot metathetic ring opening of substituted bicyclo[3.2.0]-heptenones to linear polyene ketones is described. The reaction proceeds with conservation of the endocyclic (Z)-double bond. Exo-substituted vinylcyclobutanones result in (4Z,6E)-configured trienones, while endo-substituted phenyl derivatives generate (4Z,6Z)-configured dienones.
- 出版日期2010
- 单位复旦大学
