Assembly of a Flexible 2,2 '-Oxydibenzoate and Silver(I) Ions to a Novel 3D Supramolecular Framework: Syntheses, Structure and Properties

作者：Mei Chong Zhen^*; Li Kai Hui; Li Hai Hua

来源：Zeitschrift fur Naturforschung Section B-A Journal of Chemical Sciences, 2012, 67(11): 1191-1196.

DOI：10.5560/ZNB.2012-0212

• 2,2 '-Oxydibenzoic Acid
• Silver-Organic Framework
• Hydrogen Bonding
• pi center dot center dot center dot pi Interactions
• Supramolecular Structure

Self-assembly of silver(I) cations, flexible 2,2 '-oxydibenzoate anions (L2-), and 1,2-bis(4-pyridyl)ethane (bpa) ligands affords a new three-dimensional supramolecular architecture, {[Ag-2(L)(bpa)(2)]center dot(H2O)(4)}(n) (1), which has been characterized by elemental analysis, IR, TGA, PXRD, and single-crystal X-ray diffraction. Complex 1 exhibits layers further connected through hydrogen bonding and pi center dot center dot center dot pi stacking interactions. Its photoluminescence was also investigated.

• 出版日期2012-11
• 单位华北水利水电大学