Aqua(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate

作者：Li Hong Liang^*; Liu Qi Sheng

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M847-U1049.

DOI：10.1107/S1600536808015523

In the title mononuclear complex, [Cu(NO3)(C12H10N4)(H2O)]NO3, the Cu-II ion assumes a distorted square-pyramidal geometry. There is a pi-pi stacking interaction between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid-centroid distance = 3.567 (2) angstrom and a perpendicular distance of 3.394 angstrom]. The crystal structure also contains intermolecular N-H center dot center dot center dot O, O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, linking cations and anions. In addition, there is a short intermolecular contact [2.784 (6) angstrom] between an O atom of the coordinated nitrate group and its symmetry-related atom.

• 出版日期2008-6
• 单位山东师范大学