A hydrogen bond scaffold supported synthetic heme Fe-III-O-2(-) adduct

作者:Mittra Kaustuv; Chatterjee Sudipta; Samanta Subhra; Sengupta Kushal; Bhattacharjee Hridaynath; Dey Abhishek*
来源:Chemical Communications, 2012, 48(85): 10535-10537.
DOI:10.1039/c2cc35162e

摘要

A hydrogen bonded heme-Fe-III-O-2(-) adduct is stabilized and characterized using resonance Raman and EPR spectroscopy. The low O-O vibrations of this complex are quite different from those reported for other heme-Fe-III-O-2(-) adducts.

  • 出版日期2012